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Protecting‐Group‐Controlled Surface Chemistry—Organization and Heat‐Induced Coupling of 4,4′‐Di(tert‐butoxycarbonylamino)biphenyl on Metal Surfaces
Authors:Serpil Boz  Meike Stöhr Dr  Umut Soydaner  Marcel Mayor Prof
Institution:1. Department of Physics, University of Basel, Klingelbergstrasse 82, 4056 Basel (Switzerland), Fax: (+41)?61‐267‐3784;2. Department of Chemistry, University of Basel, St. Johanns‐Ring 19, 4056 Basel (Switzerland), Fax: (+41)?61‐267‐1016;3. Forschungszentrum Karlsruhe GmbH, Institute for Nanotechnology, P.O. Box 3640, 76021 Karlsruhe (Germany)
Abstract:Like pearls on a string , molecular building blocks have been preorganized and then interlinked on a surface (see STM images). In this way both the supramolecular self‐assembly of the reactants as well as the subsequent thermal activation to release the protecting group are controlled.
image

Keywords:protecting groups  scanning tunneling microscopy  self‐assembly  surface chemistry
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