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Insertion of Amides into a Polyoxometalate |
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| Authors: | Joaquim Li Inga Huth Lise‐Marie Chamoreau Dr. Bernold Hasenknopf Dr. Emmanuel Lacôte Dr. Serge Thorimbert Dr. Max Malacria Prof. |
| Affiliation: | UPMC Univ Paris 06, CNRS UMR 7201, Institut Parisien de Chimie Moléculaire, 4 place Jussieu, 75005 Paris (France), Fax: (+33)?1 44 27 38 41 |
| Abstract: | POM alert : The incorporation of an amide oxygen atom into the framework of the Dawson‐type polyoxometalate (POM) cluster [P2V3W15O62]9? (see picture) allows the communication of electronic effects between the organic and the inorganic parts of the molecule, including fine‐tuning of the redox properties of the entire hybrid POM by the organic components, and transmission of the POM's electron‐attracting properties to the organic moiety.  |
| Keywords: | carbonyl ligands organic‐inorganic hybrid composites polyoxometalates substituent effects vanadates |