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Nanostructured Copper Oxide on Silica–Zirconia Mixed Oxides by Chemical Implantation |
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| Authors: | Daniela?Belli Dell'Amico Prof Helmut Bertagnolli Prof Fausto Calderazzo Prof Massimiliano D'Arienzo Dr Silvia Gross Dr Luca Labella Prof Marzio Rancan Dr Roberto Scotti Prof Bernd?M Smarsly Prof Ralf Supplit Dr Eugenio Tondello Prof Eric Wendel Dr |
| Institution: | 1. Dipartimento di Chimica e Chimica Industriale, Universitá di Pisa, Pisa, via Risorgimento 35, 56126 Pisa (Italy);2. Institut für Physikalische Chemie, Universit?t Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart (Germany);3. Dipartimento di Scienze dei Materiali, Università di Milano‐Bicocca via Cozzi, 53, 20125 Milano (Italy);4. CNR‐ISTM, Dipartimento di Scienze Chimiche, Universitá degli Studi di Padova and INSTM UdR, Padova, via Marzolo, 1, 35131 Padova (Italy);5. Physikalisch‐Chemisches Institut, Justus Liebig Universit?t Giessen, Heinrich‐Buff‐Ring 58, 35392 Giessen (Germany);6. Institut für Materialchemie, Technische Universit?t Wien, 1040 Vienna (Austria), Fax: (+39)?049‐827‐5161 |
| Abstract: | A new route to chemical implantation of copper(II) N,N‐dialkylcarbamato complexes on silica and nanostructured silica–zirconia matrices and subsequent thermal treatment (see scheme) is an efficient method of functionalizing the oxide matrices with nanostructured CuO. The materials have been characterized thoroughly and the effect of selected experimental parameters on the grafting reaction was investigated.  |
| Keywords: | copper oxide grafting mixed oxides nanostructures surface chemistry |