A heme-like, water-soluble iron(II) porphyrin: thermal and photoinduced properties, evidence for sitting-atop structure |
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| Authors: | Huszánk Róbert Horváth Ottó |
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| Institution: | University of Veszprém, Department of General and Inorganic Chemistry, H-8200 Veszprém, P.O. Box 158, Hungary. |
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| Abstract: | Water-soluble ferrous porphyrin (Fe(II)TPPS) was prepared by complexation reaction of free base porphyrin (H2TPPS) with iron(II) ions in the presence of iron(III)-trapping acetate buffer; the catalytic and photoinduced properties of this air-stable complex proved unambiguously its sitting-atop structure. |
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