| Synthesis and Crystal Structure of a New Ternary Mixed Ligand Complex [Cu（ampym）（bapa）Cl]（ClO4） （ampym = 2-Aminopyrimidine, bapa = Bi（3-aminopropyl）amine） |
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| 引用本文： | 许同桃,高健,许兴友,杨绪杰,陆路德,汪信.Synthesis and Crystal Structure of a New Ternary Mixed Ligand Complex [Cu（ampym）（bapa）Cl]（ClO4） （ampym = 2-Aminopyrimidine, bapa = Bi（3-aminopropyl）amine）[J].结构化学,2006,25(4):469-472. |
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| 作者姓名： | 许同桃 高健 许兴友 杨绪杰 陆路德 汪信 |
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| 作者单位： | [1]Materials Chemistry Laboratory, Nanjing University of Science ＆ Technology, Nanjing 210094, China [2]Department of Chemical Engineering, Huaihai Institute ofTectmology, Lianyungang 222005, China [3]Department of Chemical Engineering, Lianyungang Technical College, Lianyungang 222006, China |
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| 基金项目： | This project was supported by the Foundation of Science Committee of Jiangsu province (BK2005045) |
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| 摘 要： | 1 INTRODUCTION The pyrimidine substructure plays a vital role in physiological system. It occurs not only in organisms such as nucleic acids, vitamins and coenzymes1~3], but also frequently presents in commercially availa- ble drugs such as antibiotics, antiatherosclerotic and antihypertensive agent4, 5]. Studying the interaction of pyrimidine derivatives and metal ions is important as a means of understanding the role of pyrimidine ring in biological systems. This paper describes the …
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| 关 键 词： | 合成 晶体结构 三重混合配合物 铜配合物 二（3-氨基丙基）胺 2-氨基嘧啶 |
Synthesis and Crystal Structure of a New Ternary Mixed Ligand Complex [Cu(ampym)(bapa)Cl](ClO4) (ampym = 2-Aminopyrimidine, bapa = Bi(3-aminopropyl)amine) |
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| XU Tong-Tao,GAO Jian,XU Xing-You,YANG Xu-Jie,LU Lu-De,WANG Xin.Synthesis and Crystal Structure of a New Ternary Mixed Ligand Complex [Cu(ampym)(bapa)Cl](ClO4) (ampym = 2-Aminopyrimidine, bapa = Bi(3-aminopropyl)amine)[J].Chinese Journal of Structural Chemistry,2006,25(4):469-472. |
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| Authors: | XU Tong-Tao GAO Jian XU Xing-You YANG Xu-Jie LU Lu-De WANG Xin |
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| Abstract: | The title complex Cu(ampym)(bapa)Cl](ClO4) (C10H22Cl2CuN6O4) was synthesized and characterized by elemental analysis, IR and X-ray single-crystal diffraction. The crystal crystalli- zes in the orthorhombic system, space group Pna21 with a = 11.9904(12), b = 15.9796(16), c = 8.9143(9)(A), V = 1708.0(3)(A)3, Mr = 424.78, Z = 4, F(000) = 876, Dc = 1.652 g/cm3, T = 293 K, μ = 1.619 mm-1 and λ = 0.71073(A). The structure was refined to R = 0.0240 and wR = 0.0564 for 2905 observed reflections with I > 2σ(I). Flack = 0.039(12). |
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| Keywords: | 2-aminopyrimidine bi(3-aminopropyl)amine copper complex crystal structure |
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