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Spectroscopic evidence of co-insertion of carbon atoms into Li intercalated layered compounds |
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| Authors: | M. Jouanne T. Sekine C. Julien |
| Affiliation: | (1) Laboratoire de Physique des Solides, associé au CNRS, Université Pierre et Marie Curie, 4, Place Jussieu, F-75252 Paris Cedex 05, France;(2) Present address: Institute of Physics, University of Tsakuba, Ibaraki 305, Japan |
| Abstract: | Co-insertion of solvent into layered compounds intercalated with lithium has been evidenced by Raman scattering measurements. The penetration of solvated species into the host is observed in samples prepared by an electrochemical technique as well as by direct chemical reaction in n-butyl lithium. The co-insertion is evidenced by the appearance of peaks in the spectral range 1200–1800 cm–1 which are attributed to vibrations due to carbon atoms. |
| Keywords: | 68– 65 78– 30 |
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