Potential-dependent reorientation of thiocyanate on Au electrodes |
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| Authors: | Li Xiao Gewirth Andrew A |
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| Institution: | Department of Chemistry and Fredrick Seitz Materials Research Laboratory, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, USA. |
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| Abstract: | Thiocyanate (SCN) adsorption on an Au electrode is examined using surface-enhanced Raman scattering (SERS) measurements, along with detailed density functional theory (DFT) calculations. Both the calculation and the spectroscopic measurements show that three different geometries are adopted by SCN adsorption in the potential region studied (0.0 V
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