Communication Chain-foldability effect on coaggregation Evidence derived from time-resolved fluorescence spectroscopy |
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基金项目: | the National Natural Science Foundation of China Laboratory of Photochemistry and Photophysics,Institute of Photographic Chemistry,Chinese Academy of Sciences. |
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摘 要: | Very recently,we have proposed that all culprit molecules of arteriosclerosis mightpossess a common and measurable inherent property,namely,a coaggregating ten-dency.Extensive kinetic measurements of these tendencies in terms of △CAgC valueshave led to a new and surprising observation,i.e.,the cholesteryl ester with a longsaturated 18-carbon chain(CE-18)actually has a much smaller tendency towardcoaggregation than that of the ester with a“short”8-carbon chain(CE-8).Thisstate of affairs has been coined as the“chain-foldability effect”,i.e.,the 18-carbon
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