The influence of the cation on the structure of the triiodosilver(I) anion |
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| Affiliation: | 1. Department of Medical Laboratory Science, College of Medicine, University of Lagos, Lagos State, Nigeria;2. Pediatric Research Institute, Children''s Hospital Affiliated to Shandong University, Jinan 250022, China;3. Department of Biological Science (Microbiology Unit), Faculty of Natural and Applied Sciences, Arthur Jarvis University, Akpabuyo, Cross River State, Nigeria;4. Kaiti Cell Therapy, Industrial Research Institute of Jinan University, Shandong Province, China;5. Department of Microbiology, Faculty of Biological Sciences, University of Calabar, Cross River State, Nigeria;6. Department of Biology, College of Sciences, Princess Nourah bint Abdulrahman University, Riyadh 11671, Saudi Arabia;7. Department of Medical Laboratory Technology, Faculty of Applied Medical Sciences, University of Tabuk, Tabuk, Saudi Arabia;8. Department of Pure and Applied Chemistry, Faculty of Physical Sciences, University of Calabar, Cross River State, Nigeria;9. Department of Basic Medical Science, College of Medicine, Almaarefa University, Riyadh 11597, Saudi Arabia;10. Department of Physiology, Faculty of Medicine, University of Khartoum, Khartoum, Sudan;11. Department of Restorative Dentistry, Faculty of Dental Sciences, College of Medicine University of Lagos, Lagos State, Nigeria;12. Department of Pharmaceutical Chemistry, Faculty of Pharmacy, University of Lagos, Nigeria;1. College of Food and Bioengineering, Zhengzhou University of Light Industry, Zhengzhou 450001, China;2. Key Laboratory of Cold Chain Food Processing and Safety Control, Ministry of Education, Zhengzhou University of Light Industry, Zhengzhou, 450001, China |
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| Abstract: | Complexes of the type M2AgI3 (M = K, NH4, me4N, et4 N, pr4 N and bu4 N) have been prepared and characterized. The Raman spectrum of the AgI32− anion has been interpreted in terms of a C3ν symmetry. Splittings of the E modes are observed in the solid state, presumably due to a lowering of the symmetry. The influence of the size of the cation is studied. |
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