A 1H and 13C NMR study of some bis(disulfurdinitride)Ni(II) complexes with organobridging ligands |
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| Affiliation: | 1. Hubei Key Laboratory of Processing and Application of Catalytic Materials, College of Chemistry and Chemical Engineering, Huanggang Normal University, Huanggang, 438000, PR China;2. State Key Laboratory of Chemical Engineering, Stoddart Institute of Molecular Science, Department of Chemistry, Zhejiang University, Hangzhou, 310027, PR China;3. Hubei Key Laboratory of Novel Reactor and Green Chemical Technology, Wuhan Institute of Technology, Wuhan, 430205, PR China;4. Department of Chemistry, Southern University of Science and Technology (SUSTech), Shenzhen, 518055, PR China;5. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210023, PR China;1. Hubei Key Laboratory of Processing and Application of Catalytic Materials, College of Chemistry and Chemical Engineering, Huanggang Normal University, Huanggang 438000, PR China;2. Department of Chemistry, National University of Singapore, Singapore 117543, Singapore;3. Department of Chemistry, Southern University of Science and Technology (SUSTech), Shenzhen 518055, China;4. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210023, PR China;5. Stoddart Institute of Molecular Science, Zhejiang University, Hangzhou 310027, PR China |
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| Abstract: | The reaction of bis(disulfurdinitride)nickel(II), Ni(S2N2H)2, with various aldeleydes and amines yields a condensation product in which the protons of the two planar ring S2N2 ligands have been replaced by an organobridging ligand. Some of these complexes contain two chiral carbon atoms and the separation of the diasteroisomers of one complex is described. 13C NMR spectra are reported for these complexes and the assignments are in agreement with proton NMR data. The IR and electronic spectra of the complexes are also reported. |
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