Hypervalent iodine-mediated interaction of aldoximes with activated alkenes including Baylis-Hillman adducts: a new and efficient method for the preparation of nitrile oxides from aldoximes |
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| Authors: | Biswanath Das Harish Holla Gurram Mahender Joydeep Banerjee Majjigapu Ravinder Reddy |
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| Institution: | Organic Chemistry Division-I, Indian Institute of Chemical Technology, Hyderabad 500 007, India |
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| Abstract: | Treatment of aldoximes with activated alkenes in the presence of diacetoxy iodobenzene (DIB) afforded isoxazolines in high yields. The method has been applied for the preparation of polyfunctional isoxazolines from Baylis-Hillman adducts. |
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| Keywords: | Aldoxime Alkene Baylis-Hillman adduct DIB Isoxazoline |
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