Lewis acid promoted aldol reaction of fluorinated silyl enol ethers from new fluoroacetylsilane derivatives |
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| Authors: | Woo Jin Chung |
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| Institution: | Department of Chemistry, University at Albany, State University of New York, 1400 Washington Ave., Albany, NY 12222, USA |
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| Abstract: | New fluorinated silyl enol ethers with various trialkylsilyl groups were synthesized. Various fluorinated β-hydroxy ketones were synthesized by Lewis acid promoted aldol reaction of silyl enol ethers with diverse aldehydes. Reactivity of various trialkylsilyloxy groups toward Lewis acid was also studied. |
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| Keywords: | Fluorinated ketone Aldol reaction Lewis acid Fluorinated silyl enol ether |
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