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Oxovanadium(V)-catalyzed enantioselective Meerwein-Ponndorf-Verley cyanation of aldehydes using acetone cyanohydrin |
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| Authors: | Akira Watanabe |
| Institution: | Department of Chemistry, Faculty of Science, Graduate School, Kyushu University 33, 6-10-1 Hakozaki, Higashi-ku, Fukuoka 812-8581, Japan CREST, Japan Science and Technology Agency (JST), Japan |
| Abstract: | Oxovanadium(V)(salen) complex 4 was found to catalyze Meerwein-Ponndorf-Verley cyanation of aliphatic aldehydes with good to high enantioselectivity. This cyanation showed a positive nonlinear effect. |
| Keywords: | Asymmetric catalysis Meerwein-Ponndorf-Verley cyanation Cyanohydrin Oxovanadium(V)(salen) complex |
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