p-(3-Carboxy- and 3-carboxymethyl-1-adamantyl)calix[4]arenes: synthesis and arming with amino acid units |
| |
| Authors: | Elvira A Shokova Vladimir V Kovalev |
| |
| Institution: | a Laboratory of Macrocyclic Receptors, Chemistry Department, Moscow State University, Lenin’s Hills, 119992 Moscow, Russia
b State Research Institute of Chemistry and Technology of Elementorganic Compounds, 111123 Moscow, Russia |
| |
| Abstract: | Adamantylcalix4]arenes carboxylated at the upper rim have been synthesized by a convenient one-step procedure from p-H-calix4]arene and carboxylated 1-adamantanols. Selective and exhaustive lower rim alkylation along with upper rim modification by amino acid fragments have been carried out. Preliminary evaluation of the novel N-linked peptidocalixarenes as ionophores for ion-selective electrodes is reported. |
| |
| Keywords: | Carboxylated calixarenes Upper rim adamantylation Peptidocalixarenes ISE |
| 本文献已被 ScienceDirect 等数据库收录！ |
