Unexpected interconnection of the 7-norbornenyl and 3-nortricyclcyl/5-norbornen-2-yl cations |
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| Authors: | Robert A Moss Xiaolin Fu |
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| Institution: | Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, New Brunswick, NJ 08903, USA |
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| Abstract: | Fragmentation of syn-7-norbornenyloxychlorocarbene provides products derived from both 7-norbornenyl cation-chloride anion pairs and from 3-nortricyclyl/2-norbornen-5-yl cation-chloride anion pairs. A 5,7-hydride shift within the 7-norbornenyl cation is proposed to interconnect the two cation systems. |
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