New chiral ligands and iron(III) complexes based on 2,6-bis(1-benzyl-4-isopropyl-4-methyl-4,5-dihydro-1H-imidazol-5-on-2-yl)pyridines |
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Institution: | a Department of Organic Chemistry, Faculty of Chemical Technology, University of Pardubice, Nám. ?s. Legií 565, 532 10 Pardubice, Czech Republic b Department of Inorganic Chemistry, Faculty of Science, Charles University, Hlavova 2030, 128 43 Prague 2, Czech Republic |
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Abstract: | New ligands and their complexes with iron(III) chloride have been suggested and prepared: (R,S)-, (R,R)- and (S,S)-2,6-bis(1-benzyl-4-isopropyl-4-methyl-4,5-dihydro-1H-imidazol-5-on-2-yl) pyridines. Both the ligands and their complexes were characterised by 1H and 13C NMR spectroscopy, optical rotation and X-ray diffraction. |
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