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The first total syntheses of (±)-Preussomerins K and L using 2-arylacetal anion technology
Authors:Ernesto Quesada
Affiliation:Department of Chemistry, University of York, Heslington, York, YO10 5DD, United Kingdom
Abstract:The first syntheses of newly isolated members of the Preussomerin family, Preussomerins K and L, are reported. Key steps include the functionalisation of a 2-arylacetal anion, one-pot Friedel-Crafts cyclisation-deprotection and reductive opening of epoxides.
Keywords:Total synthesis   Natural products   Preussomerins   Arylacetal anion
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