Ru3(CO)12-catalyzed intramolecular allylic transfer reaction of tethered carbonyl group and allylic acetate moiety |
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| Authors: | Chan-Mo Yu Sungwon Lee Young-Taek Hong Seok-Keun Yoon |
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| Institution: | Department of Chemistry and Laboratory for Metal-Catalyzed Reactions, Sungkyunkwan University, Suwon 440-746, South Korea |
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| Abstract: | A ruthenium catalyzed intramolecular allylic transfer reaction of allylic acetates containing aldehydes or ketones to form cis-homoallylic cyclopentanols and cyclohexanols as a major component is described. The use of Ru3(CO)12 (1 mol %) to promote reaction results in a convenient procedure for intramolecular allylation of carbonyl functionalities. |
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| Keywords: | Allylation Carbonyl Catalyst Cyclization Ruthenium |
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