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Stereoselective synthesis of the cis-decalin subunit of vinigrol via three pericyclic reactions in cascade
Authors:Louis Morency
Affiliation:Department of Chemistry, 10 Marie Curie, University of Ottawa, Ottawa, Canada K1N 6N5
Abstract:Synthesis of the cis-decalin portion of vinigrol using a tandem oxy-Cope/Claisen/ene reaction is described. This three pericyclic reaction cascade proves to be a valuable synthetic tool in the construction of such systems.
Keywords:Vinigrol   Cope   Ene   Claisen   Tandem reaction
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