Asymmetric Pauson-Khand reaction with chiral, electron-deficient mono- and bis-phosphine ligands |
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| Authors: | Denes Konya Andrew E Greene |
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| Institution: | Université Joseph Fourier, LEDSS (UMR 5616-CNRS), BP 53X, 38041 Grenoble, France |
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| Abstract: | The intermolecular Pauson-Khand reaction between norbornene and dicobalt carbonyl complexes of phenylacetylene substituted with chiral phosphorus ligands has been investigated. High yields (?98%) and enantiomeric excesses of up to 56% have been observed. |
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| Keywords: | Pauson-Khand chiral phosphines ligand |
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