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A mild and efficient palladium-catalyzed homocoupling of lithium alkynyltriisopropoxyborates: a new route to synthesis of 1,3-diynes
Authors:Chang Ho Oh  V.Raghava Reddy
Affiliation:Department of Chemistry, Hanyang University, Sungdong-Gu, Seoul 133-791, South Korea
Abstract:Lithium alkynyltriisopropoxyborates were homocoupled in the presence of palladium acetate and DPEPhos. This protocol allows a new efficient route to synthesis of 1,3-diynes under very mild conditions.
Keywords:Palladium   Catalyst   Homocoupling   Diyne   Borate
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