trans-Stereoselective intramolecular crossed pinacol coupling of aromatic 1,4-, 1,5-, and 1,6-diketones by electroreduction |
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| Authors: | Naoki Kise Yousuke Shiozawa Nasuo Ueda |
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| Institution: | Department of Biotechnology, Faculty of Engineering, Tottori University, Koyama, Tottori 680-8552, Japan |
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| Abstract: | Electroreduction of aromatic 1,4-, 1,5-, and 1,6-diketones in the presence of chlorotrimethylsilane and triethylamine gave four-, five-, and six-membered 1,2-diols with trans-stereoselectivity. |
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| Keywords: | Electroreduction Crossed pinacol coupling 1 4-Diketones 1 5-Diketones 1 6-Diketones 1 2-Diols |
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