Direct aminoalkylation of cycloalkanes through dimethylzinc-initiated radical process |
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| Authors: | Ken-ichi Yamada |
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| Institution: | Graduate School of Pharmaceutical Sciences, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan |
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| Abstract: | Cycloalkyl radicals were directly generated from cycloalkanes via C-H bond cleavage by the action of dimethylzinc-air and underwent an addition reaction with N-tosylimines, giving aminoalkylation products in fair to high yields. |
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| Keywords: | Radicals Dimethylzinc Imines Cycloalkanes |
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