A verification of the photolytic decomposition pathways of 3-<em>tert</em>-butyl-3-chlorodiazirine based on the application of the C<sub>60</sub> probe technique期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

*A verification of the photolytic decomposition pathways of 3-tert-butyl-3-chlorodiazirine based on the application of the C₆₀ probe technique*

Authors:	Midori O. Ishitsuka Takatsugu Wakahara Michael T.H. Liu

Affiliation:	^a Center for Tsukuba Advanced Research Alliance, Department of Chemistry, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8577, Japan ^b Graduate School of Science and Technology, Niigata University, Niigata, Niigata 950-2181, Japan ^c Department of Chemistry, University of Prince Edward Island, Charlottetown, Prince Edward Island, C1A4P3 Canada ^d Department of Theoretical Studies, Institute for Molecular Science, Okazaki, Aichi 444-8585, Japan

Abstract:	C₆₀ acts as a mechanistic probe for the formation of carbene and for the rearranged product via the excited state in the photolysis of 3-t-butyl-3-chlorodiazirine.

Keywords:	C₆₀ Diazirine Photolytic decomposition Carbene RIES process
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