Rhodium catalysed hydroformylation of unsaturated esters |
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| Authors: | Matthew L Clarke |
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| Institution: | School of Chemistry, University of St. Andrews, St. Andrews, Fife, KY16 9ST, UK |
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| Abstract: | Rhodium catalysed hydroformylation of unsaturated esters has been studied. A pronounced temperature dependence was observed on the regioselectivity and catalytic activity for these reactions, and under the appropriate conditions, it is possible to obtain preferentially either linear or quaternary products. A quaternary selective hydroformylation of methyl atropate to give 1,3-aldehydic esters has also been developed. |
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| Keywords: | Hydroformylation Alkoxycarbonylation Regioselective C-C bond formation Quaternary carbons Phosphite Rhodium |
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