Synthesis of BEDT-TTF derivatives with carboxylic ester and amide functionalities |
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Authors: | R.James Brown Gemma Camarasa Peter Day |
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Affiliation: | a School of Science, The Nottingham Trent University, Clifton Lane, Nottingham NG11 8NS, UK b The Royal Institution of Great Britain, 21 Albemarle Street, London W1S 4BS, UK |
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Abstract: | Synthetic routes to BEDT-TTF derivatives bearing side chain carboxylic ester and amide groups are reported. Methyl ET-ethanoate was prepared in five steps from vinylacetic acid; amide groups were installed early in the synthesis by mixed anhydride methods before the final coupling reaction. |
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Keywords: | Organosulfur donors Hydrogen bonding BEDT-TTF Amides |
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