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Synthesis of BEDT-TTF derivatives with carboxylic ester and amide functionalities
Authors:R.James Brown  Gemma Camarasa  Peter Day
Affiliation:a School of Science, The Nottingham Trent University, Clifton Lane, Nottingham NG11 8NS, UK
b The Royal Institution of Great Britain, 21 Albemarle Street, London W1S 4BS, UK
Abstract:Synthetic routes to BEDT-TTF derivatives bearing side chain carboxylic ester and amide groups are reported. Methyl ET-ethanoate was prepared in five steps from vinylacetic acid; amide groups were installed early in the synthesis by mixed anhydride methods before the final coupling reaction.
Keywords:Organosulfur donors   Hydrogen bonding   BEDT-TTF   Amides
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