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Recent developments in the synthesis of heterocyclic derivatives by PdI2-catalyzed oxidative carbonylation reactions |
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| Authors: | Bartolo Gabriele Giuseppe Salerno Gian Paolo Chiusoli |
| Affiliation: | a Dipartimento di Scienze Farmaceutiche, Università della Calabria, 87036 Arcavacata di Rende, Cosenza, Italy b Dipartimento di Chimica, Università della Calabria, 87036 Arcavacata di Rende, Cosenza, Italy c Dipartimento di Chimica Organica e Industriale, Università di Parma, Parco Area delle Scienze, 43100 Parma, Italy |
| Abstract: | A simple catalytic system, consisting of PdI2 in conjunction with an excess of KI, has proven to be very valuable for the direct one-step synthesis of a variety of heterocyclic derivatives by oxidative carbonylation of suitably functionalized alkynes. The same catalyst also promoted the oxidative carbonylation of β-amino alcohols to oxazolidin-2-ones with unprecedented catalytic efficiencies for this kind of reaction. |
| Keywords: | Alkynes β-Amino Alcohols Carbonylation Heterocycles Oxidative Carbonylation Palladium |
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