A tandem radical cyclization route to tricyclo[4.3.n.0]alkanes |
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| Authors: | Hee-Yoon Lee |
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| Affiliation: | Center for Molecular Design and Synthesis, Department of Chemistry and BK21 School of Molecular Science, Korea Advanced Institute of Science and Technology, Daejeon, 305-701, Korea |
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| Abstract: | A facile route to tricyclo[4.3.n.01,5]alkane skeletons from conjugated cyclic enones was developed through tandem free radical cyclization reaction sequence involving the cyclopropylmethyl radical mediated rearrangement. The scope and limitation of the reaction was investigated. |
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| Keywords: | Radical Cyclization Mechanism |
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