Unusual reaction of β-hydroxy α-diazo carbonyl compounds with TsNHNCHCOCl/Et3N |
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Authors: | Weifeng Shi |
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Affiliation: | Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China |
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Abstract: | The reaction of β-hydroxy α-diazo carbonyl compounds with TsNHNCHCOCl/Et3N gave β-(p-tolylsulfonyl) α,β-unsaturated carbonyl compounds or β-(p-tolylsulfonyl) α-diazo esters. The reaction mechanism is discussed. |
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