Application of an air stable Pd oxazoline complex for Heck, Suzuki, Sonogashira and related C-C bond-forming reactions |
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| Authors: | Robert A Gossage Hilary A Jenkins Paras N Yadav |
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| Institution: | a The Chester Woodleigh Small Laboratory of Inorganic Chemistry, 6 University Avenue, Elliott Hall, Department of Chemistry, Acadia University, Wolfville, Nova Scotia, Canada B4P 2R6
b Department of Chemistry, St. Mary’s University, Halifax, Nova Scotia, Canada B3H 3C3 |
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| Abstract: | The novel complex trans-PdCl2(η1-N-2-ethyl-2-oxazoline)2] is shown to be an active and oxidatively robust catalyst for C-C bond-forming reactions (Heck, Sonogashira, Ullman, Suzuki), which can be carried out in air without rigorous solvent/substrate purification and in the absence of additional free ligand. |
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| Keywords: | C-C bond formation Palladium Heck Sonogashira Suzuki Catalysis Oxazoline |
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