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Synthesis of chiral 2,2′-dipyridylamines and their use in the copper-catalyzed asymmetric allylic oxidation of cyclohexene
Authors:Carsten Bolm  Jean-Cédric Frison  Jacques Le Paih  Christian Moessner
Institution:Institut für Organische Chemie der RWTH Aachen, Professor-Pirlet-Str. 1, D-52056 Aachen, Germany
Abstract:Chiral dipyridylamines have been synthesized by N-arylation reactions, and the applicability of those compounds to the copper-catalyzed asymmetric allylic oxidation of cyclohexene was demonstrated.
Keywords:Allylic oxidation  N-Arylation  Copper catalysis  2  2&prime  -Dipyridylamines
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