DBU-assisted 1,3,2-oxathiaphospholane ring-opening condensation with selected O-, S-, N- and C-nucleophiles |
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| Authors: | Konrad Misiura |
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| Institution: | Department of Bioorganic Chemistry, Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza 112, 90-363 ?ód?, Poland |
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| Abstract: | The reactivity of protected thymidine 3′-O- and 5′-O-(2-thio-1,3,2-oxathiaphospholanes) towards various nucleophiles in the presence of DBU is presented and mechanistic implications are discussed. |
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| Keywords: | Oxathiaphospholane DBU Nucleophilic substitution Bifunctional catalysis |
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