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Highly selective synthesis of 1-(silyl)-1-(boryl)ethenes via a ruthenium-catalyzed silylative coupling reaction |
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| Authors: | Magdalena Jankowska Cezary Pietraszuk Marek Zaidlewicz |
| Affiliation: | a Department of Organometallic Chemistry, Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780 Poznań, Poland b Department of Chemistry, Nicolaus Copernicus University, Gagarina 7, 87-100 Toruń, Poland |
| Abstract: | An efficient silylative coupling of trisubstituted vinylsilanes with dialkoxy(vinyl)boranes is described. Under optimum conditions the reaction offers a selective route to 1-(silyl)-1-(boryl)ethenes, which are potentially attractive intermediates in organic synthesis |
| Keywords: | Silylative coupling Vinylsilanes Vinylboranes Ruthenium complexes |
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