Reactivity of a kinetically stabilized 1,3,6-triphosphafulvene toward some nucleophiles |
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| Authors: | Shigekazu Ito |
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| Institution: | Department of Chemistry, Graduate School of Science, Tohoku University Aoba, Sendai 980-8578, Japan |
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| Abstract: | A kinetically stabilized 1,3,6-triphosphafulvene displayed regioselective reactivity toward nucleophiles at the external phosphorus atom (position 6) to afford the corresponding phosphinodiphospholide anions, which gave phosphinodiphospholes after quenching with electrophiles, as well as being readily reduced by sodium naphthalenide suggesting properties similar to fulvenes. |
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| Keywords: | Phosphaalkenes Conjugated system Nucleophilic reaction Reduction Regioselectivity |
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