The first synthesis and absolute configuration of glaucescenolide |
| |
| Authors: | Hirosato Takikawa Keiko Ueda Mitsuru Sasaki |
| |
| Institution: | Department of Biosystems Science, Graduate School of Science and Technology, Kobe University, Rokkodai 1-1, Nada-ku, Kobe 657-8501, Japan |
| |
| Abstract: | The first synthesis of glaucescenolide (1), a cytotoxic sesquiterpene isolated from the liverwort, Schistochila glaucescens, was achieved by starting from 2,2,6-trimethylcyclohexanone (2). The absolute configuration of the naturally occurring 1 was confirmed as 5S,7S,10R. |
| |
| Keywords: | Sesquiterpene Schistochila glaucescens Cytotoxicity Enzymatic resolution |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
