Syntheses, luminescence switching, and electrochemical studies of photochromic dithienyl-1,10-phenanthroline zinc(II) bis(thiolate) complexes |
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Authors: | Ngan Tung-Wan Ko Chi-Chiu Zhu Nianyong Yam Vivian Wing-Wah |
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Institution: | Department of Chemistry and HKU-CAS Joint Laboratory on New Materials, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China. |
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Abstract: | A series of zinc(II) diimine bis(thiolate) complexes with photochromic diarylethene-containing phenanthroline ligands was synthesized, and their photophysical and photochromic properties were studied. The X-ray crystal structures of two of these complexes have been characterized. All complexes exhibit strong 3LLCT phosphorescence at 510-620 nm in the solid state at 77 and 298 K and in EtOH-MeOH glass at 77 K. Detailed studies revealed that the absorption, emission, and electrochemical properties of the complexes could be readily switched via the photochromic ring-closing and ring-opening reactions. |
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