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Helical structures from an isotropic homopolymer model
Authors:Magee James E  Vasquez Victor R  Lue Leo
Institution:School of Chemical Engineering and Analytical Science, The University of Manchester, P.O. Box 88, Sackville Street, Manchester M60 1QD, United Kingdom. j.magee@manchester.ac.uk
Abstract:We present Monte Carlo simulation results for square-well homopolymers at a series of bond lengths. Although the model contains only isotropic pairwise interactions, under appropriate conditions this system shows spontaneous chiral symmetry breaking, where the chain exists in either a left- or a right-handed helical structure. We investigate how this behavior depends upon the ratio between bond length and monomer radius.
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