Rate constants for photochemically induced hydrogen abstraction calculated from spin trapping rates |
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Authors: | G. Mó ger, P. Simon A. Rockenbauer |
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Affiliation: | (1) Central Research Institute for Chemistry of the Hungarian Academy of Sciences, Budapest, Hungary |
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Abstract: | ESR spin trapping method has been applied to calculate the rate constant for -hydrogen abstraction from ethylbenzene by triplet anthraquinone: k1=1.1×107 M–1 s–1 (error of estimation 25%).
( ) -CH : k1=1.1×107 M–1–1 ( 25%) |
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