| Total Synthesis of Two 4, 5-Dioxo-seco-eudesmane Sesquiterpenes |
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| 作者姓名： | LiJingFANG ChenXiZHANG JinChunCHEN GuoJunZHENG YuLinLI |
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| 作者单位： | StateKeyLaboratoryofAppliedOrganicChemistry,InstituteofOrganicChemistry,LanzhouUniversity,Lanzhou730000 |
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| 摘 要： | A facile synthetic route to two seco-eudesmane, 4, 5-dioxo-10-epi-4, 5-seco-γ-eudesmane (1) and 4, 5-dioxo-10-epi-4, 5-seco-γ-eudesmol (2) from ( )-dihydrocarvone has been described. Avoiding expensive reagents, this highly economic method especially suits for the synthesis of 4, 5-seco-eudesman-type and ophianon-type sesquiterpenes with a double bond at position 11 and 12.
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| 关 键 词： | 4 5-二氧-桉叶烷 二氢香芹酮 倍半萜烯 合成方法 |
Total Synthesis of Two 4, 5-Dioxo-seco-eudesmane Sesquiterpenes |
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| LiJingFANG ChenXiZHANG JinChunCHEN GuoJunZHENG YuLinLI.Total Synthesis of Two 4, 5-Dioxo-seco-eudesmane Sesquiterpenes[J].Chinese Chemical Letters,2005,16(5):569-571. |
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| Authors: | Li Jing FANG Chen Xi ZHANG Jin Chu n CHEN Guo Jun ZHENG Yu Lin LI State Key Laboratory of Applied Organic Chemistry |
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| Institution: | Li Jing FANG,Chen Xi ZHANG,Jin Chu n CHEN,Guo Jun ZHENG,Yu Lin LI State Key Laboratory of Applied Organic Chemistry,Institute of Organic Chemistry,Lanzhou University,Lanzhou 730000 |
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| Abstract: | |
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| Keywords: | (+)-Dihydrocarvone 4 5-dioxo-seco-eudesmane sesquiterpenes |
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