An efficient electrochemical synthesis of diamino-o-benzoquinone: mechanistic and kinetic evaluation of the reaction of azide ion with o-benzoquinone |
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| Authors: | Nematollahi Davood Afkhami Abbas Tammari Esmail Shariatmanesh Tahere Hesari Mahdi Shojaeifard Maryam |
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| Affiliation: | Faculty of Chemistry, University of Bu-Ali-Sina, Hamadan, 65174, Iran. nemat@basu.ac.ir |
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| Abstract: | An efficient method for the synthesis of diamino-o-benzoquinone based on the Michael reaction of electrochemically generated o-benzoquinone with azide ion is described, as well as an estimation of the homogeneous rate constant (k(obs)) of the reaction of o-benzoquinone with azide ion by the digital-simulation method. |
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