Synthesis of Acylphosphonates by a Palladium‐Catalyzed Phosphonocarbonylation Reaction of Aryl Iodides with Phosphites |
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| Authors: | Yusuke Masuda Dr Naoki Ishida Prof Dr Masahiro Murakami |
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| Institution: | Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto 615‐8510 (Japan) |
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| Abstract: | Acylphosphonates are conveniently synthesized from aryl iodides by a palladium‐catalyzed reaction with dialkyl phosphites under an atmospheric pressure of carbon monoxide. The reaction demonstrates the first example of the use of phosphorus nucleophiles in related metal‐catalyzed carbonylation reactions. |
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| Keywords: | carbonylation homogeneous catalysis palladium phosphorus synthetic methods |
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