Redox‐Mediated Synthesis of a Fe3O4–MnO2 Nanocomposite for Dye Adsorption and Pseudocapacitance |
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Authors: | Ramkrishna Sahoo Dr Mukul Pradhan Anindita Roy Soumen Dutta Chaiti Ray Prof?Dr Yuichi Negishi Prof?Dr Anjali Pal Prof?Dr Tarasankar Pal |
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Institution: | 1. Department of Chemistry, Indian Institute of Technology, Kharagpur, India;2. Department of Applied Chemistry, Tokyo University of Science, Tokyo, Japan;3. Department of Civil Engineering, Indian institute of Technology, Kharagpur, India |
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Abstract: | A logically chosen redox reaction of submerged Fe0 in an aqueous KMnO4 solution has been reported. The template‐free reaction conditions produced gram amounts of a hierarchical flowerlike Fe3O4–MnO2 nanocomposite. More precisely, freshly prepared Fe0 nanoparticles were prepared from air‐free hot water under submerged conditions using a door magnet. The black Fe0 particles were oxidized in water quantitatively by KMnO4 in the solution phase and the nanocomposite was prepared. The material has been used as a dye adsorbent and the representative cationic dye uptake, recovery, and recycling of the dye becomes easy owing to the ferromagnetic properties and surface negative charge of the material. The nanocomposite also showed a higher specific capacitance (327 F g?1 at 10 mV s?1) than the reported values of pure MnO2 and Fe3O4. The material exhibited a high energy density as well as a high power density, and remained stable even after a large number of charge–discharge cycles. |
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Keywords: | adsorption capacitors electrochemistry nanostructures redox chemistry |
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