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Crystal and Molecular Structures of Phosphonolactone Derivatives of Chromone
Authors:Magdalena Ma?ecka  Werner Massa  El?bieta Budzisz
Institution:(1) Department of Crystallography and Crystal Chemistry, University of tódź, 90-236, tódź, Pomorska, 149/153, Poland;(2) Department of Chemistry, University of Marburg, Hans-Meerwein-Strasse, D-35032 Marburg, Germany;(3) Faculty of Pharmacy, Department of Bioorganic Chemistry, Medical University of tódź, 90-151, tódź, Muszyńskiego 1, Poland
Abstract:The crystal structure of chromone hydrazonium salt (±)-1-hydroxy-1-oxo-3-phenyl-1,3-dihydro-1λ5-2,1-oxaphospholo4,5-b]-4H-1-benzopyran-4-one (2) and its acid (±)-1-hydroxy-1-oxo-3-phenyl-1,3-dihydro-1λ5-2,1-oxaphospholo4,5-b]-4H-1-benzopyran-4-one (3) have been solved. Condensed rings are almost planar, the P atom adopts nearly tetragonal geometry. The molecular packing is influenced by inter- and intramolecular contacts, which can be recognized as hydrogen bonds.
Keywords:Chromone derivatives  X-ray structure analysis  hydrogen bonds
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