Supramolecular squares of dirhodium(ii) tetracarboxylate: combining carboxylate-exchange and metal-ligand coordination for self-assembly |
| |
| Authors: | Lok H Tong Sarah Clifford Antoine Gomila Sylvain Duval Laure Guénée Alan F Williams |
| |
| Affiliation: | Department of Inorganic and Analytical Chemistry, University of Geneva, Sciences II, 30, quai Ernest Ansermet, 1211 Geneva 4, Switzerland. alan.williams@unige.ch. |
| |
| Abstract: | Square self-assemblies are obtained from dirhodium(ii) tetracarboxylate complexes using an isonicotinate-type ligand to act as an equatorial ligand to one dirhodium unit and an axial ligand to another. It is shown that the supramolecular squares are formed selectively out of a number of possible compounds in the dynamic carboxylate exchange library. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
