Encapsulation of atmospheric CO(2) by a self-assembled decanuclear cadmium complex via unfamiliar perchlorato and carbonato bridges |
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| Authors: | Ana M García-Deibe Cristina Portela-García Matilde Fondo Antonio J Mota Jesús Sanmartín-Matalobos |
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| Affiliation: | Departamento de Química Inorgánica, Facultad de Química, Universidad de Santiago de Compostela, 15782-Santiago de Compostela, Spain. jesus.sanmartin@usc.es. |
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| Abstract: | A decanuclear Cd complex has been found as a carbonate-containing capsule. The structure strongly resembles a ten-blade waterwheel with a central carbonate ligand surrounded by two superimposed Cd(5)O(5) crowns with a pentagonal antiprism-like disposition. The capsule is doubly capped by two pentadentate perchlorate anions. |
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