The selenite-capped polyoxo-4-aurate(iii), [Au(III)(4)O(4)(Se(IV)O(3))(4)](4-) |
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| Authors: | Yixian Xiang Natalya V Izarova Florian Schinle Oliver Hampe Bineta Keita Ulrich Kortz |
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| Institution: | Jacobs University, School of Engineering and Science, P.O. Box 750 561, 28725 Bremen, Germany. u.kortz@jacobs-university.de n.izarova@jacobs-university.de. |
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| Abstract: | The discrete heteropolyaurate Au(III)(4)O(4)(Se(IV)O(3))(4)](4-) () represents only the second member of this class ever reported, and was synthesized via one-pot room temperature condensation in aqueous medium. was structurally characterized in the solid state and in solution by single-crystal XRD, TGA, FT-IR, (77)Se NMR, mass spectrometry and electrochemistry. |
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