Encapsulated reagents for nitrosation |
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| Authors: | Zyryanov Grigory V Rudkevich Dmitry M |
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| Affiliation: | Department of Chemistry & Biochemistry, University of Texas at Arlington, Arlington, Texas 76019-0065, USA. |
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| Abstract: | [reaction: see text] A novel class of stable, mild, and size-shape-selective nitrosating agents for secondary amides is introduced. These are based on reversible entrapment and release of reactive nitrosonium species by calix[4]arenes. The NO(+) encapsulation controls the reaction selectivity. |
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