Novel synthetic approach to the 8,10-dimethyl anti-syn-anti-perhydrophenanthrene skeleton |
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| Authors: | Coltart Don M Danishefsky Samuel J |
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| Affiliation: | The Laboratory for Bioorganic Chemistry, The Sloan-Kettering Institute for Cancer Research, 1275 York Avenue, New York, New York 10021, USA. |
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| Abstract: | [reaction: see text] An efficient and highly stereocontrolled approach to the 8,10-dimethyl anti-syn-anti-perhydrophenanthrene carbon skeleton starting with the Wieland-Miescher ketone is described. The approach centers on a Diels-Alder-angular methylation-deoxygenation sequence. |
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