| 用大孔吸附树脂从发酵液中提取顺-1,2-二羟基-3,5-环己二烯 |
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| 引用本文： | 马祺祥,陈金春,邹冰,陈国强.用大孔吸附树脂从发酵液中提取顺-1,2-二羟基-3,5-环己二烯[J].离子交换与吸附,2004,20(5):407-414. |
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| 作者姓名： | 马祺祥 陈金春 邹冰 陈国强 |
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| 作者单位： | 清华大学生物科学与技术系,北京,100084 |
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| 基金项目： | 国家“863”高新技术项目 (编号2002AA333030) |
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| 摘 要： | 顺-1，2-二羟基-3，5-环己二烯(DHCD)是化学合戍高性能材料1．4-聚苯的单体。本文系统地研究了用大孔吸附树脂从发酵液中提取DHCD的方法，进行了树脂的筛选．考查了流速．溶液中葡萄糖浓度等因素对吸附能力的影响．选择极性的NKA-Ⅱ树脂作为吸附剂，采用12ml／mm的流速．用甲醇作为洗脱剂对DHCD发酵液进行提取使提取率达到82，2％．大大优于现有的用二氟甲烷萃取的工艺。
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| 关 键 词： | 顺-1，2-二羟基-3，5-环己二烯 DHCD 大孔吸附树脂 提取 |
| 文章编号： | 1001-5493(2004)05-0407-08 |
| 修稿时间： | 2004年4月30日 |
SEPARATION OF CIS-1,2-DIHYDROXYCYCLOHEXA-3,5-DIENE FROM FERMENTATION BROTH USING MACROPOROUS RESINS |
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| MA Qixiang,CHEN Jinchun,ZOU Bing,CHEN Guoqiang.SEPARATION OF CIS-1,2-DIHYDROXYCYCLOHEXA-3,5-DIENE FROM FERMENTATION BROTH USING MACROPOROUS RESINS[J].Ion Exchange and Adsorption,2004,20(5):407-414. |
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| Authors: | MA Qixiang CHEN Jinchun ZOU Bing CHEN Guoqiang |
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| Institution: | MA Qixiang CHEN Jinchun ZOU Bing CHEN Guoqiang Department of Biological Sciences and Biotechnology Tsinghua University,Beijing 100084,China |
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| Abstract: | Cis-1,2-dihydroxycyclohexa-3,5-diene (DHCD) is the monomer for the chemical synthesis of poly-para-phenylene which is a material with excellent electrical properties. The method of extracting DHCD from the fermentation with macroporous resin is investigated systematically in this paper, including the selecting of resins and finding the factors to the capacities of absorption, such as the flow speed and the concentration of the glucose. The polar NKA-II resin is chosen as the absorbent to extract DHCD, with the speed of 1.2 ml/min and using methanol as the solvent. As a result, the extraction rate is 82.2%, much better than the existing technique with methylene chloride as a solvent. |
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| Keywords: | Cis-1 2-dihydroxycyclohexa-3 5-diene DHCD Macroporous resin Extraction |
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