| 红外光谱振动模式分解及应用 |
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| 引用本文： | 郭纯孝 刘悦贤. 红外光谱振动模式分解及应用[J]. 高等学校化学学报, 1993, 14(1): 89-92 |
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| 作者姓名： | 郭纯孝 刘悦贤 |
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| 作者单位： | 吉林大学化学系, 长春 130023 |
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| 摘 要： | 本文用群论方法推出多原子分子正则振动模式的可约表示特征标公式,在IBM微机上实现程序化,使红外光谱振动模式分解更加简便、实用。并且给出ABn(n=2～12)构型分子和碳原子簇C_n(n=20,24,50,60,70,84)的振动模式不可约表示。
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| 关 键 词： | 红外光谱 振动模式分解 碳原子簇 |
| 收稿时间： | 1992-01-25 |
Reduction and Application of Normal Vibrational Models in Infrared Spectrum |
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| GUO Chun-Xiao,LIU Yue-Xian. Reduction and Application of Normal Vibrational Models in Infrared Spectrum[J]. Chemical Research In Chinese Universities, 1993, 14(1): 89-92 |
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| Authors: | GUO Chun-Xiao LIU Yue-Xian |
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| Affiliation: | Department of Chemistry, Jilin University, Changchun, 130023 |
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| Abstract: | The character of reducible representation for normal models of multi-atomic molecular system is formulated by group theoretical approach. The formula is programmed in IBM personal computer , which makes the reduction of normal models in infared spectrum simple and practical, The ine-ducible representation of normal models for some AB.(n = 2~ 12) molecules and carbon clusters Ca(w =-20, 24, 50, 60, 70, 84) are also presented. |
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| Keywords: | Infrared spectrum Reduction of vibration models Carbon clusters |
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